Merck 806373.0100 Sodium borohydride

fine granular for synthesis

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Ambalaj Miktarı: 100 gr

(2024 güncel fiyat)

Ambalaj Fiyatı: 67,66 € + %20 KDV

 

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Ürün Fiyatı: 67,66 €

Ürün Özellikleri

CAS # EC Number Hill Formula Chemical Formula Molar Mass
16940-66-2 241-004-4 H₄BNa NaBH₄ 37.83 g/mol
Description
Catalogue Number 806373
Synonyms Sodium tetrahydridoborate

Merck 806373.0100 | Sodium borohydride fine granular for synthesis 100G

Product Information
CAS number 16940-66-2
EC number 241-004-4
Hill Formula H₄BNa
Chemical formula NaBH₄
Molar Mass 37.83 g/mol
HS Code 2850 00 20

Applications
Application Sodium borohydride fine granular for synthesis. Sodium borohydride CAS No. 16940-66-2, EC Number 241-004-4. Sodium borohydride MSDS (material safety data sheet) or SDS here.

Physicochemical Information
Boiling point 500 °C (decomposition)
Density 1.07 g/cm3 (20 °C)
Explosion limit 3.02 %(V)
Flash point 69 °C not applicable
Ignition temperature 220 °C
Melting Point 400 °C (slow decomposition)
pH value 11 (10 g/l, H₂O, 20 °C)
Bulk density 350 – 500 kg/m3
Solubility 550 g/l (slow decomposition)

Toxicological Information
LD 50 oral LD50 Rat 160 mg/kg
LD 50 dermal LD50 Rabbit 230 mg/kg

Safety Information according to GHS
Hazard Pictogram(s)


Hazard Statement(s) H260: In contact with water releases flammable gases which may ignite spontaneously.
H301 + H311: Toxic if swallowed or in contact with skin
H314: Causes severe skin burns and eye damage.
Precautionary Statement(s) P280: Wear protective gloves/ protective clothing/ eye protection/ face protection.
P301 + P330 + P331: IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P308 + P310: IF exposed or concerned: immediately call a POISON CENTER or doctor/ physician.
P402 + P404: Store in a dry place. Store in a closed container.
RTECS ED3325000
Storage class 4.3 Hazardous materials, which set free flammable gases upon contact with water
WGK WGK 2 water endangering
Disposal 26
Alkali and alkaline-earth metals should be taken up in an inert solvent and neutralized by adding 2-propanol (Cat. No. 100995) dropwise with stirring. Should the reaction be more violent than expected, conversion should be carried out with tert-butanol or octanol. Caution: This reaction produces hydrogen, which can form explosive mixtures; take necessary precautions. When the reaction has ceased, add water dropwise; neutralize; container D. In the case of alkali or alkaline-earth borohydrides, add methanol (Cat. No. 106008) with stirring; in the case of alkali or alkaline-earth amides and hydrides, organoaluminium and organotin hydrides, add 2-propanol (Cat. No. 100995) dropwise. The substances, which are usually in solid form, should be previously suspended in an ether! When the respective reaction has ceased, hydrolize with water; then neutralize. Container D or E. Lithium aluminium hydride must also be destroyed by slurrying in an ether. Under an inert gas and with thorough stirring, add dropwise a 1:4 mixture of ethyl acetate (Cat. No. 822277) and the ether used to prepare the slurry. Always ensure thorough mixing (stirring)! Container A.

Safety Information
Hazard Symbols Flammable
Toxic
Categories of danger highly flammable, toxic, corrosive
R Phrase R 15-24/25-35
Contact with water liberates extremely flammable gases.Toxic in contact with skin and if swallowed.Causes severe burns.
S Phrase S 14-26-36/37/39-43-45
Keep away from oxidising and acidic substances as well as heavy-metal compounds.In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Wear suitable protective clothing, gloves and eye/face protection.In case of fire, use sand. Never use water.In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).

Storage and Shipping Information
Storage Store below +30°C.

Transport Information
Declaration (railroad and road) ADR, RID UN 1426 , 4.3, I
Declaration (transport by air) IATA-DGR UN 1426 , 4.3, I
Declaration (transport by sea) IMDG-Code UN 1426 , 4.3, I

Specifications
Assay (hypochlorite) ≥ 98.0 %
Identity (ICP-OES) passes test

8.06373.0100

Sodium borohydride fine granular for synthesis.

Sodium borohydride CAS No. 16940-66-2, EC Number 241-004-4. Sodium borohydride MSDS (material safety data sheet) or SDS here.

Sodyum borohidrür

Laboratuvar Kimyasalları

Ürün Özellikleri:

100 gr 67,66 € + %20 KDV